Electrochemical Aspects of the Synthesis of Iron Particles

Abstract

The preparation of Fe-particles by reduction of FeSO₄ with either sodium borohydride or lithium triethylborohydride in water, and reverse micelles in rapeseed and mineral oil phases is described in electrochemical terms. The influence of surfactants on the electrochemical parameters and resulting size of iron particles was studied as well. The resulting size of Fe-particles synthesized in water (with and without surfactants) correlates with the determined values of open circuit potential (OCP): the more negative OCP, the obtained Fe-particles are bigger, because values of OCP correspond to different range of polarization determined for the reduction of Fe²⁺. The sizes of Fe-particles synthesized in water or oil phases without surfactants using LiBEt₃H are less than using NaBH₄ because of electrochemical factors. By varying oils and surfactants it is possible to obtain opposite results as in water phase: smaller Fe-particles obtained using NaBH₄ than using LiBEt₃H. It is explained by the simultaneous influence of electrochemical and steric stabilization factors, and the last one becomes dominating in some cases.

DOI: http://dx.doi.org/10.5755/j01.ms.18.3.2429