Preliminary Study of the Pozzolanic Activity of Dumped Mine Wastes Obtained from the North Bohemian Basin in the Czech Republic

Konstantinos SOTIRIADIS, Petr ŠAŠEK, Radek ŠEVČÍK, Pavel SCHMIDT, Michal ŘEHOŘ, Alberto VIANI

Abstract


Three dumped raw materials, a tuff and two bentonites, obtained from two mining sites at the North Bohemian basin in the Czech Republic, have been studied in order to evaluate them as pozzolanic admixtures in lime mortars for employment in restoration of cultural heritage objects. After thermal activation (800 °C; 5 h), their pozzolanic properties were compared with those of commercial metakaolin. Quantitative phase analysis with the Rietveld method from X-ray powder diffraction patterns, morphological observations, as well as the Frattini and the modified Chapelle tests were performed. In addition, lime mortars, incorporating the fired materials, were prepared and subjected to simultaneous thermal analysis after a 28-day initial curing (20 ± 1 °C; 60 ± 5 % RH). The results showed that all three materials possess pozzolanic activity. However, when employed in lime mortars they did not result in formation of pozzolanic reaction products. Two methods were proposed to improve their reactivity; grinding to obtain finer particle size and removal of quartz content where necessary.

DOI: http://dx.doi.org/10.5755/j01.ms.23.1.14864


Keywords


pozzolanic activity, dumped mine wastes, lime mortars, thermal analysis

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Print ISSN: 1392–1320
Online ISSN: 2029–7289