How to Analyse Metal Hydride Decomposition Temperatures Using a Sieverts’ Type Hydriding-Dehydriding Apparatus and Hydrogen-Storage Characteristics for an MgH2–Based Alloy

Abstract

In this work, a method to analyze metal hydride decomposition temperatures (the onset temperature of the metal hydride decomposition and the temperature for the maximum ratio of released gas quantity change with temperature change), of prepared samples were investigated using a Sieverts’ type hydriding-dehydriding apparatus, in which a back-pressure regulator was employed. The quantity of the gas released under 1.0 bar H₂ was measured as the temperature was increased with a heating rate of 4 K/min. The variation in the ratio of released hydrogen quantity H_d change with temperature T change, dH_d/dT, as a function of temperature was obtained and from the variation in dH_d/dT with T, the metal hydride decomposition temperatures were analyzed. This analysis method can be used instead of thermal analysis methods such as thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) analysis, differential thermal analysis (DTA), and thermal desorption spectroscopy (TDS) analysis. For this analysis, a sample with a composition of 89 wt.% MgH₂ + 4.9 wt.% Ni + 1.7 wt.% Zn(BH₄)₂ + 1.0 wt% NaCl + 1.7 wt.% Ti + 1.7 wt % Fe (named MgH₂-Ni-Zn(BH₄)₂-NaCl-Ti-Fe) sample was prepared by planetary ball milling. In the prepared MgH₂-Ni-Zn(BH₄)₂-NaCl-Ti-Fe sample, it is believed that MgH₂ begins to decompose at about 575 K and dH_d/dT reaches its peak at about 610 K.

DOI: http://dx.doi.org/10.5755/j01.ms.24.1.17664